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Structure controlling and process scale-up in the fabrication of nanomaterials

Chunzhong LI,

《化学科学与工程前沿（英文）》 2010年 第4卷 第1期   页码 18-25 doi: 10.1007/s11705-009-0305-3

摘要： Nanotechnology is already having a significant commercial impact, and will very certainly have a much greater impact in the future. The research on process engineering and scale-up will be very important for the commercial production and application of nanomaterials, because the properties and structure of nanomaterials are not only determined by the nucleation and growth process, but also strongly affected by the engineering properties, such as the mixing, the heat and mass transfer, and also the distribution of temperature, concentration, etc. This paper will present some research work in our laboratory on the fabrication of nanomaterials. Based on the chemical engineering principle and methods, many kinds of novel nanomaterials can be synthesized and their structure can be easily controlled through adjusting the parameters of the fluid mixing, and the distribution of temperature, residence time and concentration, etc. By using the micro-mixing, heat and mass transfer and reaction control methods, the host-guest nanocomposites have been assembled and assumed as the novel electroanalytical sensing nanobiocomposite materials. Based on the principles of chemical engineering, the manufacturing technologies for magnetic powders, calcium carbonate, and titanium dioxide have been developed for commercial-scale production, and the largest production scale has reached 15 kt/year.

关键词： scale-up     significant commercial     electroanalytical     engineering     laboratory    

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Erratum to: On the potential of iPhone significant location data to characterize individual mobility

《环境科学与工程前沿（英文）》 2022年 第16卷 第9期 doi: 10.1007/s11783-022-1556-1

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On the potential of iPhone significant location data to characterize individual mobility for air pollution

《环境科学与工程前沿（英文）》 2022年 第16卷 第5期 doi: 10.1007/s11783-022-1542-7

摘要：

● We evaluated the accuracy of iPhone data in capturing time-activity patterns.

关键词： Air pollution exposure     Human mobility     iPhone     Significant Location     Smartphone data    

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Significant progress in solution of nonlinear equations at displacement of structure and heat transfer

M. R. AKBARI,D. D. GANJI,M. NIMAFAR,A. R. AHMADI

《机械工程前沿（英文）》 2014年 第9卷 第4期   页码 390-401 doi: 10.1007/s11465-014-0313-y

摘要：

In this paper, we aim to promote the capability of solving two complicated nonlinear differential equations: 1) Static analysis of the structure with variable cross section areas and materials with slope-deflection method; 2) the problem of one dimensional heat transfer with a logarithmic various surface A(x) and a logarithmic various heat generation G(x) with a simple and innovative approach entitled “Akbari-Ganji’s method” (AGM). Comparisons are made between AGM and numerical method, the results of which reveal that this method is very effective and simple and can be applied for other nonlinear problems. It is significant that there are some valuable advantages in this method and also most of the differential equations sets can be answered in this manner while in other methods there is no guarantee to obtain the good results up to now. Brief excellences of this method compared to other approaches are as follows: 1) Differential equations can be solved directly by this method; 2) without any dimensionless procedure, equation(s) can be solved; 3) it is not necessary to convert variables into new ones. According to the aforementioned assertions which are proved in this case study, the process of solving nonlinear equation(s) is very easy and convenient in comparison to other methods.

关键词： AGM     extended surface     heat transfer     slope-deflection method    

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Solution properties and self-association of multi-blocks like copolymer P(AM/AA) prepared by template copolymerization

ZHANG Yuxi, WU Feipeng, LI Miaozhen, WANG Erjian

《化学科学与工程前沿（英文）》 2007年 第1卷 第1期   页码 68-71 doi: 10.1007/s11705-007-0014-8

摘要： The association and properties of multi-block like copolymers (TP) of acrylamide (AM) and acrylic acid (AA) prepared by template copolymerization in aqueous solution were studied. The results showed that the copolymers of this type exhibited a significant structure effect compared with that of similar random copolymers (CP) obtained by copolymerization in the absence of template. Decreasing the value of pH or adding Ca ion to the copolymer solution will make phase separation occur. The TEM images demonstrated that the phase separation caused by Ca ion was due to the formation of extensively intermolecular cross-linking. With the increase of the pH value of copolymer solution, the changes of the solution viscosity was similar with that of homopolyacrylic acid, which originally increased and then decreased. But the increase range of template copolymer was higher than that of homopolyacrylic acid. TEM images indicated that at the maximal viscosity the copolymer obtained in the presence of template formed coiled aggregates.

关键词： aqueous solution     homopolyacrylic     copolymer solution     significant structure     presence    

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Distinct community assembly processes underlie significant spatiotemporal dynamics of abundant and rare

《环境科学与工程前沿（英文）》 2022年 第16卷 第6期 doi: 10.1007/s11783-021-1513-4

摘要：

• Season and landform influenced spatiotemporal patterns of abundant and rare taxa.

关键词： Rare taxa     Biogeography     Community assembly     Bacterioplankton     The Yangtze River    

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Repetitive transcranial magnetic stimulation causes significant changes of chemical substances in the

GUO Tiecheng, CAO Xuebing, XIA Limin

《医学前沿（英文）》 2008年 第2卷 第4期   页码 406-409 doi: 10.1007/s11684-008-0078-y

摘要： More and more studies have reported the usefulness of repetitive transcranial magnetic stimulation (rTMS) in the treatment of stroke patients. This article is to explore if rTMS can cause changes of such chemical substances as N-acetylaspartate (NAA), choline (Cho) and creatine (Cr) in the surrounding area of experimental intracerebral hematoma of rabbits. A total of 36 rabbits were randomly divided into 3 groups: a control group (group A), a sham rTMS group (group B) and an rTMS group (group C). The experimental intracerebral hemorrhage (ICH) was induced by intracerebral injection of self-body blood of the animals in groups B and C, while those of the group A serving as controls were injected with normal saline. The rabbits of groups B and C were treated with sham and real rTMS, respectively, but those of group A were not. The contents of chemical substances including NAA, Cho and Cr in the perihematomal brain tissues were measured by using H-magnetic resonance spectroscopy (H-MRS) 12 hours, 72 hours, 1 week and 2 weeks after the experimental ICH was induced. The results show that the contents of NAA, Cr and NAA/Cr ratio were decreased significantly, but Cho, Cho/Cr increased significantly in groups B and C ( < 0.01) as compared against those in group A. A comparison between the groups B and C revealed that the contents of NAA, Cr, NAA/Cr were higher, but Cho and Cho/Cr were significantly lower in group C than those in group B ( < 0.01). It is concluded that rTMS could result in changes of the chemical substance contents in perihematomal brain tissues, which leads to neuroprotective effects in the brain.
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Significant potential of Solid Oxide Fuel Cell systems for distributed power generation and carbon neutrality

《能源前沿（英文）》 2022年 第16卷 第6期   页码 879-882 doi: 10.1007/s11708-022-0850-8

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Type 2 diabetic patients with non-alcoholic fatty liver disease exhibit significant haemorheological

Hui Dong, Fu’er Lu, Nan Wang, Xin Zou, Jingjing Rao

《医学前沿（英文）》 2011年 第5卷 第3期   页码 288-293 doi: 10.1007/s11684-011-0127-9

摘要： Haemorheological abnormalities have been described in diabetes mellitus, as well as in non-alcoholic fatty liver disease (NAFLD). However, the relationship between the changes in liver fat content and haemorheology is unknown. The current study aims to show the correlation between haemorheological parameters and intrahepatic lipid content (IHLC) in patients with type 2 diabetes. The serum biochemical markers, such as fasting plasma glucose (FPG), haemoglobin A1c (HbA1c), liver enzymes, lipid profiles, and haemorheological properties, were examined. IHLC was quantified using proton magnetic resonance spectroscopy ( H-MRS) scanning of the liver. A significant correlation was observed between IHLC and whole blood viscosity at high, middle, and low shear rates. IHLC also positively correlated with haematocrit, the reduced whole blood viscosity at low and middle shear rates, and the erythrocyte aggregation index. Diabetic patients with NAFLD exhibited significant haemorheological abnormalities compared with patients without NAFLD. In summary, haemorheological disorders are linked to non-alcoholic fatty liver in type 2 diabetes.

关键词： diabetes mellitus     type 2     haemorheology     non-alcoholic fatty liver disease    

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重大建设工程技术创新网络形成机理与运行机制分析

王孟钧,张镇森

《中国工程科学》 2011年 第13卷 第8期   页码 62-66

摘要：

笔者从重大建设工程技术创新的特点和现状分析入手，剖析制约重大建设工程技术创新的核心障碍，建立面向重大建设工程技术创新网络的基本架构，分析其形成起点、演化路径和整合方式，探讨技术创新网络的动力机制、协同机制和学习机制，为建立跨组织协同的新型技术创新模式，提高重大建设工程技术创新效率和水平提供理论依据。

关键词： 重大建设工程     技术创新网络     形成机理     运行机制    

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Defective Nickle–Iron Layered Double Hydroxide for Enhanced Photocatalytic NO Oxidation with Significant

Xiaoyu Li,Xiaoshu Lv,Jian Pan,Peng Chen,Huihui Peng,Yan Jiang,Haifeng Gong,Guangming Jiang,Li'an Hou,

《工程（英文）》 doi: 10.1016/j.eng.2023.06.017

摘要： Photocatalysis offers a sustainable avenue for the oxidative removal of low concentrations of NOx from the atmosphere. Layered double hydroxides (LDHs) are promising candidate photocatalysts owing to their unique layered and tunable chemical structures, and the abundant hydroxide (OH−) moieties on their surfaces that are hydroxyl radical (•OH) precursors. However, inferior charge separation and limited active sites on an LDH hinder its practical applications. Herein, we developed a facile N2H4-driven etching (et) approach that introduces dual Ni2+ and OH− vacancies (Niv and OHv) into NiFe-LDH nanosheets (referred to as NiFe-LDH-et) that facilitate improved charge-carrier separation and the formation of active Lewis acidic sites (Fe3+ and Ni2+ exposed at OHv). In contrast to inert pristine LDH, NiFe-LDH-et actively removes NO when illuminated with visible light. Specifically, Ni76Fe24-LDH-et etched in 1.50 mmol·L−1 N2H4 solution removes 32.8% of the NO from continuously flowing air (NO-feed concentration: ∼500 parts per billion (ppb)) when illuminated with visible light, thereby outperforming most reported catalysts. Experimental and theoretical data reveal that the dual vacancies promote the production of reactive oxygen species (•O2− and •OH) and the adsorption of NO on the LDH. In-situ spectroscopy revealed that NO is preferentially adsorbed at Lewis acidic sites, particularly exposed Fe3+ sites, and then converted into NO+ that is subsequently oxidized to NO3− without the formation of any of the more toxic NO2 intermediate, thereby alleviating risks associated with its production and emission.

关键词： Vacancies     Layered double hydroxide     NO     +     Photocatalysis     NO removal    

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Analytical method of capsizing probability in the time domain for ships in the random beam seas

LIU Liqin, TANG Yougang, LI Hongxia

《结构与土木工程前沿（英文）》 2007年 第1卷 第3期   页码 361-366 doi: 10.1007/s11709-007-0048-5

摘要： The methods for constructing safe basins of ships and predicting their survival probability in random waves were studied. The nonlinear differential equation of the rolling motion of ships in random beam seas was established considering nonlinear damping, nonlinear restoring moment, and random waves. The random rolling differential equation was solved in the time domain by applying the harmonic acceleration method and by synthetically considering the instantaneous state of ships and the narrowband wave energy spectrum. The numerical simulation of random capsizing course was brought forward, the safe basins were constructed for safe navigation, and the survival probabilities of ships were calculated. As an example, the safe basins on the rolling initial value plane were constructed for a 30.27-meter-long fishing vessel according to different initial conditions and random wave parameters. The survival probabilities of the fishing vessel under different significant wave heights were predicted. Thus, the survival probabilities of ships in random seas can be predicted quantitatively by the proposed method.

关键词： different     survival probability     different significant     nonlinear differential     narrowband    

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基于HY-2高度计波形数据的高分辨率有效波高反演算法研究

王桂忠,张杰,苗洪利,李国强,王鑫

《中国工程科学》 2014年 第16卷 第6期   页码 60-64

摘要：

有效波高是描述海况的重要参量之一，利用高度计遥感获取有效波高已在海洋研究中获得广泛应用。本文基于海洋二号（HY-2）卫星高度计波形数据，发展了一种高分辨率有效波高反演算法，采用中误差对反演得到的20 Hz有效波高进行筛选，有效提高了测量精度。通过该方法对1 个轨的波形数据进行有效波高反演，统计结果表明：与针对1 s 回波反演的有效波高比较，利用该方法可将有效波高观测分辨率提高约15 倍，精度约为0.44 m；利用HY-2 高度计20 Hz 波形数据反演的有效波高精度可靠，可用其进行高分辨率的相关海洋研究。

关键词： HY-2     有效波高     反演算法     高分辨率    

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Emergency design framework: a satellite preliminary scheme design

TENG Hongfei, WANG Yishou, ZHANG Bao

《机械工程前沿（英文）》 2007年 第2卷 第2期   页码 184-192 doi: 10.1007/s11465-007-0031-9

摘要： The emergency design of mechanical products or equipment (such as a satellite) is significant for disaster relief when the natural disasters occur. Most of us are unaware about the little information that is available in literature about emergency designs. Against the background of the preliminary scheme design of satellite payloads, emergency design was studied in the case of natural disasters. We presented some definitions about emergency design. Then, we proposed the basic ideas of how to realize the emergency design. These ideas were inspired by two aspects: 1) the evolutionary algorithms, the agent, the human-computer cooperation, and the collaborative design theory; 2) the emergency behaviors in ant colonies. Following the ideas, first we constructed the human computer cooperation agents (hereinafter called the HC-Agents) that combine the human intelligence with evolutionary algorithms. These HC-Agents had specific features like the division of labor in the ant colony. Second, we developed the multiagents cooperative design system on the basis of a hybrid P2P (peer-to-peer) model. Therefore, the emergency design system has shown some capabilities, such as anti-interference, adaptation, and rapid response.

关键词： significant     intelligence     P2P     hereinafter     computer cooperation    

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Analysis of the treatment outcomes of esophageal variceal bleeding patients from multiple centers in China

WANG Zhiqiang

《医学前沿（英文）》 2008年 第2卷 第2期   页码 171-173 doi: 10.1007/s11684-008-0031-0

摘要： This study aimed to investigate the treatment outcomes of esophageal variceal bleeding (EVB) in China. A total of 1087 cases were collected from 19 hospitals in 16 large and medium sized cities across China between January 1st, 2005 and January 1st, 2006. There were 313 cases (29.0%) of mild (<400 mL), 494 cases (45.8%) of moderate (400–1500 mL) and 272 cases (25.2%) of severe (>1500 mL) bleeding. Successful hemostasis was achieved in 89.8% of cases. Seven hundred and eighty-five cases were treated by medication with a hemostasis rate of 91.8%. Seventy-one cases were treated using a Sengstaken-Blakemore tube with a hemostasis rate of 54.9%. Thirty-seven cases were treated with emergency endoscopic variceal ligation with a hemostasis rate of 83.8%. Seventy-seven cases were treated with endoscopic sclerotherapy with a hemostasis rate of 94.8%. Forty-three cases were treated with emergency surgical operation with a hemostasis rate of 95.3%. Sixty-six cases were treated with combined therapy with a hemostasis rate of 97.0%. There was a significant difference ( < 0.01) in the successful hemostasis rate between different treatments. The overall mortality was 10.1%, among which 6.6% was directly caused by bleeding. The multivariate logistic regression analysis shows that the severity of bleeding, treatment methods, liver dysfunction and activation of hepatitis were predictive factors for successful hemostasis. Most cases of EVB were mild and moderate in severity. The first-line treatment for EVB is medication. Emergency endoscopic intervention has not been widely available yet. The overall management outcome of EVB has been improved.

关键词： significant difference     predictive     medication     first-line treatment     bleeding    

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标题 作者 时间 类型 操作

Structure controlling and process scale-up in the fabrication of nanomaterials

Chunzhong LI,

期刊论文

Erratum to: On the potential of iPhone significant location data to characterize individual mobility

期刊论文

On the potential of iPhone significant location data to characterize individual mobility for air pollution

期刊论文

Significant progress in solution of nonlinear equations at displacement of structure and heat transfer

M. R. AKBARI,D. D. GANJI,M. NIMAFAR,A. R. AHMADI

期刊论文

Solution properties and self-association of multi-blocks like copolymer P(AM/AA) prepared by template copolymerization

ZHANG Yuxi, WU Feipeng, LI Miaozhen, WANG Erjian

期刊论文

Distinct community assembly processes underlie significant spatiotemporal dynamics of abundant and rare

期刊论文

Repetitive transcranial magnetic stimulation causes significant changes of chemical substances in the

GUO Tiecheng, CAO Xuebing, XIA Limin

期刊论文

Significant potential of Solid Oxide Fuel Cell systems for distributed power generation and carbon neutrality

期刊论文

Type 2 diabetic patients with non-alcoholic fatty liver disease exhibit significant haemorheological

Hui Dong, Fu’er Lu, Nan Wang, Xin Zou, Jingjing Rao

期刊论文

重大建设工程技术创新网络形成机理与运行机制分析

王孟钧,张镇森

期刊论文

Defective Nickle–Iron Layered Double Hydroxide for Enhanced Photocatalytic NO Oxidation with Significant

Xiaoyu Li,Xiaoshu Lv,Jian Pan,Peng Chen,Huihui Peng,Yan Jiang,Haifeng Gong,Guangming Jiang,Li'an Hou,

期刊论文

Analytical method of capsizing probability in the time domain for ships in the random beam seas

LIU Liqin, TANG Yougang, LI Hongxia

期刊论文

基于HY-2高度计波形数据的高分辨率有效波高反演算法研究

王桂忠,张杰,苗洪利,李国强,王鑫

期刊论文

Emergency design framework: a satellite preliminary scheme design

TENG Hongfei, WANG Yishou, ZHANG Bao

期刊论文

Analysis of the treatment outcomes of esophageal variceal bleeding patients from multiple centers in China

WANG Zhiqiang

期刊论文